Alternative to hydroquinone in preparing offset plates

Number

141-EN

Section

General Section

Use

Sector

Printing and reproduction of recorded media

Function

Adsorbent

Process

Treatment of articles by dipping and pouring

Product category

Adsorbents

Application

preparation of offset printing plates

Abstract

Hydroquinone is an ingredient in photographic developers for the preparation of offset printing plates. Using thermal instead of chemical engraving allows for the elimination of hydroquinone.

Substituted substances

Hydroquinone

CAS No. 123-31-9 EC No. 204-617-8 Index No. 604-005-00-4

Chemical group

Phenols

Classification: hazard statements

H351 Suspected of causing cancer
H341 Suspected of causing genetic defects
H302 Harmful if swallowed
H318 Causes serious eye damage
H317 May cause an allergic skin reaction
H400 Very toxic to aquatic life

Reliability of information

Internet information: data are from an internet document and only a basic and partial evaluation could be performed

Reason substitution

CMR
skin/respiratory sensitizing

Other type of alternative

Laser treatment of printing plate.

Hazard Assessment

Substance to be substituted: Hydroquinone is: 1A or 1B carcinogen (CLP Regulation) and a sensitiser (H317, H334; CLP Regulation) as listed in the Substance Database according to SUBSPORTplus Screening Criteria (SDSC). Alternative substance: Non-chemical alternative. Hazards not assessed in SUBSPORTplus.

Description of Substitution

Preparation of offset printing plates uses chemical products containing hydroquinone, a skin sensitiser and a suspected carcinogen and mutagen. An alternative process, that eliminates hydroquinone, uses an aluminium plate covered by thermoplastic particles that are melted by exposure to laser, making them adherent to the plate, in the areas that need to be covered by ink. In the area that needs to remain clean (without ink) the non-activated particles are brushed away.

Case/substitution evaluation

Hydroquinone can be eliminated by a technology with good performance. Implementing the technology requires technological investments for a specific machine. This substitution is successful in the complete elimination of chemical hazards to human health

State of implementation

In use

Date and place of implementation

France

Availability ofAlternative

Alternative available on the market

Type of information supplier

Authority

Contact

INSTITUT NATIONAL DE RECHERCHE ET DE SÉCURITÉ pour la prévention des accidents du travail et des maladies professionnelle), France, http://www.inrs.fr www.inrs.fr

Type of publication and availability

Fact sheet, in French

Publication source: author, company, institute, year

The Fact sheet was developed by CNAMTS and INRS, France and published by INRS on its website in 2007.

Publication source

Type of publication and availability

http://www.inrs.fr/accueil/produits/mediatheque/doc/publications.html?refINRS=FAS%2012

Date, reviewed

December 11, 2020