Number
123-EN
Section
General Section
Use
Sector
Building and construction work
Function
Monomers
Process
Manual activities involving hand contact
Product category
polymer ppaations and cimpounds
Application
Flooring
Abstract
In the construction of the headquarters of the Center for Research and Energetic Resources (CIRCE) in Zaragoza, Spain, it was decided to avoid the use of toxic materials. PVC floorings were substituted with natural linoleum, as PVC contains vinyl chloride a carcinogenic substance and phthalates, which are endocrine disruptors.
Substituted substances
Di(2-ethylhexyl) phthalate
CAS No. 117-81-7 EC No. 204-211-0 Index No. 607-317-00-9
Chemical group
Carboxylic acid esters
Classification: hazard statements
H360FD May damage fertility. May damage the unborn child
Other adverse effects
The substance is: 2B carcinogen (IARC), on the OSPAR list of substances of possible concern, endocrine disruptor cat. 1 (EU EDC database) as listed in the Substance Database according to SUBSPORT Screening Criteria (SDSC).
Diisononyl phthalate
CAS No. 28553-12-0 EC No. 249-079-5 Index No.
Chemical group
Phtalates
Other adverse effects
The substance is: endocrine disruptor (SIN List), endocrine disruptor cat. 2 (EU EDC database) as listed in the Substance Database according to SUBSPORT Screening Criteria (SDSC).
Benzyl butyl phthalate
CAS No. 85-68-7 EC No. 201-622-7 Index No. 607-430-00-3
Chemical group
Phthalate
Classification: hazard statements
H360Df May damage the unborn child. Suspected of damaging fertility
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
Other adverse effects
The substance is: on the OSPAR list of substances of possible concern, endocrine disruptor cat. 1 (EU EDC database) as listed in the Substance Database according to SUBSPORT Screening Criteria (SDSC).
Diethyl phthalate
CAS No. 84-66-2 EC No. 201-550-6 Index No.
Chemical group
Phtalates
Other adverse effects
The substance is: endocrine disruptor (SIN List), endocrine disruptor cat. 1 (EU EDC database) as listed in the Substance Database according to SUBSPORT Screening Criteria (SDSC).
Chloroethylene
CAS No. 75-01-4 EC No. 200-831-0 Index No. 602-023-00-7
Chemical group
Organochlorine compounds
Classification: hazard statements
H220 Extremely flammable gas
H350 May cause cancer
Other adverse effects
The substance is: 1 carcinogen (IARC), as listed in the Substance Database according to SUBSPORT Screening Criteria (SDSC).
Alternative Substances
Linseed oil
CAS No. 8001-26-1 EC No. 232-278-6 Index No.
Chemical group
Fatty acids
Reliability of information
Evidence of implementation: there is evidence that the solution was implemented and in use at time of publication
Reason substitution
other toxic effects
ecotoxicity
Hazard Assessment
Substances to be substituted: Di(2-ethylhexyl) phthalate is: 2B carcinogen (IARC), endocrine disruptor cat. 1 (EU EDC database), edlists.org: Substances identified as endocrine disruptors at EU level as listed in the Substance Database according to SUBSPORTplus Screening Criteria (SDSC). This substance may damage fertility and may damage the unborn child. Diisononyl phthalate is: endocrine disruptor (SIN List), endocrine disruptor cat. 2 (EU EDC database) as listed in the Substance Database according to SUBSPORTplus Screening Criteria (SDSC). Benzyl butyl phthalate is: 1 A or 1B carcinogen (CLP Regulation), on the OSPAR list of substances of possible concern, endocrine disruptor cat. 1 (EU EDC database), edlists.org: Substances identified as endocrine disruptors at EU level as listed in the Substance Database according to SUBSPORTplus Screening Criteria (SDSC). This substance may damage the unborn child and is suspected of damaging fertility, is very toxic to aquatic life and is very toxic to aquatic life with long lasting effects. Diethyl phthalate is: endocrine disruptor (SIN List), endocrine disruptor cat. 1 (EU EDC database) as listed in the Substance Database according to SUBSPORTplus Screening Criteria (SDSC). The substance is: 1 carcinogen (IARC), 1A or 1B carcinogen (CLP Regulation) as listed in the Substance Database according to SUBSPORTplus Screening Criteria (SDSC). This substance may cause cancer and is an extremely flammable gas. Alternative substance: The alternative Linseed oil is a natural oil with no risks.
Description of Substitution
During the construction of buildings many materials are used that contain toxic substances. These substances pose a risk to the health of construction workers and may pose a threat to the health of the users of the building, as many toxic substances may be released gradually throughout the life of the building. The new headquarters of the Center for Research and Energetic Resources (CIRCE) in Zaragoza, Spain, aimed to be a model of bioconstruction and sustainability, as well as a showcase of new technologies for energy savings and eco-efficiency. Built to a have a low ecological footprint, it is a zero emissions building throughout its life-cycle, it is environmentally friendly and an example for future buildings. Opened in July 2010, the building had been funded by the EU through FEDER funds and by the Government of Aragon. As general paving for offices and corridors, natural linoleum was installed instead of common PVC flooring. PVC floorings contain hazardous chemicals such as vinyl chloride, a carcinogen and neurotoxin, and phthalates, which are endocrine disrupting substances. There are several alternative materials for floorings including stone, wood, ceramic, etc. In this case natural linoleum was chosen, a material which was widely used before the appearance of vinyl floors. Linoleum is based on solidified linseed oil mixed with cork powder, natural resins and different pigments. The main advantages of natural linoleum are that it doesn’t contain toxic substances, is very tough, water resistant and has bacteriostatic properties. Because of these properties it is widely used in hospitals.
Case/substitution evaluation
Natural linoleum is free of hazards so substitution using this product is a better choice than PVC flooring.
State of implementation
Full capacity
Date and place of implementation
2009, Spain
Enterprise using the alternative
http://www.jebens-architecture.eu
Availability ofAlternative
On the market
Type of information supplier
User
Contact
Other solutions
Natural stone
Date, reviewed
December 11, 2020