Substitution of 2-methoxyethanol with ethanol in double esterase analysis of blood samples.

Number

085-EN

Section

General Section

Use

Sector

Health services
Scientific research and development

Function

Other

Process

Other

Product category

laboratory chemicals

Application

Double esterase analysis

Abstract

2-Methoxyethanol is a part of two different incubation media. These incubation medium are used in double esterase analysis, a kind of blood analysis.

Substituted substances

2-Methoxyethanol

CAS No. 109-86-4 EC No. 203-713-7 Index No. 603-011-00-4

Chemical group

Glycol ethers

Classification: hazard statements

H226 Flammable liquid and vapour
H360FD May damage fertility. May damage the unborn child
H332 Harmful if inhaled
H312 Harmful in contact with skin
H302 Harmful if swallowed

Alternative Substances

Ethanol

CAS No. 64-17-5 EC No. 200-578-6 Index No. 603-002-00-5

Chemical group

Alcohol

Classification: hazard statements

H225 Highly flammable liquid and vapour

Other adverse effects

The substance is: 1 carcinogen (IARC), as listed in the Substance Database according to SUBSPORT Screening Criteria (SDSC).

Reliability of information

Evidence of implementation: there is evidence that the solution was implemented and in use at time of publication

Reason substitution

CMR

Hazard Assessment

The alternative, ethanol, is included in in the database of hazardous substances according to SUBSPORT screening criteria (SDSC), however only for presence in alcoholic beverages, which this is not. It is also highly flammable. 2-methoxyethanol holds the R-phrases R10, 60, 61, 20/21/22.

Description of Substitution

Incubation is one of the steps included in double esterase analysis. The sample which typically comes from blood or bone marrow is air-dried and then fixated. After this the smears of blood or bone marrow are incubated in two steps. In the first step the sample is incubated in an incubation medium for 15 minutes. After this the sample is incubated in a different incubation medium for an additional 5 minutes. Both of these incubations mediums usually contain 2-methoxyethanol. In this substitution however, 2-methoxyethanol has been substituted with ethanol.

The advantages with using ethanol instead of 2-methoxyethanol is that ethanol is less hazardous and therefore less restricted and also easier to work with. A further advantage with the substitution is that there are no changes in the original process when changing from 2-methoxyethanol to ethanol which makes the substitution easy to perform.
There are currently no known disadvantages with the substitution. An important thing to note however is that the colouring of the samples are different when using 2-methoxyethanol compared to ethanol. The difference is not important though as the cells are just as easy to count which is the purpose of the analysis.

Case/substitution evaluation

2-methoxyethanol holds a number of properties making it very inappropriate from the workers' health perspective, including reproductive toxicity and harmful by inhalation, contact or swallowed. To substitute this with ethanol is very beneficial, if the ethanol is handled with care due to its flammability.

State of implementation

Full capacity

Enterprise using the alternative

Department for Clinical chemistry at Sahlgrenska University Hospital.

Availability ofAlternative

On the market.

Type of information supplier

User

Contact

Research analyst at the department for Clinical chemistry at Sahlgrenska University Hospital.

Date, reviewed

February 27, 2020