Number
449-EN
Section
General Section
Use
Sector
Manufacture of fine chemicals
Function
Cleaning agent
Process
Treatment of articles by dipping and pouring
Manual maintenance(cleaning and repair) of machinery
Other
Product category
washing ad cleaning products
Application
Cleaning of contaminated machine parts (artifical fibre production)
Abstract
The company manufactures artificial fibres such as acetate yarn, and used large amounts of acetone to wash the contaminated machine parts. Acetone is highly flammable, causes serious eye irritation and has neurotoxic properties. Due to workers health concerns the company wanted to find a safer alternative. With the encouragement and support of the LIFE Fit for REACH project, the company tested an innovative cleaner containing natural microorganisms that degrade oils, greases and particle impurities. The cleaner proved to be a suitable alternative which was technologically feasible, and safer for workers and the environment.
Substituted substances
Acetone
CAS No. 67-64-1 EC No. 200-662-2 Index No. 606-001-00-8
Chemical group
Ketones
Classification: hazard statements
H225 Highly flammable liquid and vapour
H336 May cause drowsiness or dizziness
H319 Causes serious eye irritation
Alternative Substances
Alcohols, C12-14 (even numbered), ethoxylated propoxylated
CAS No. 68439-51-0 EC No. 931-986-9 Index No.
Chemical group
Reliability of information
Evidence of implementation: there is evidence that the solution was implemented and in use at time of publication
Reason substitution
neurotoxicant
other toxic effects
other reasons
Hazard Assessment
Substances to be substituted: Acetone is harmonised classified: Flam. Liq. 2 (H225), Eye Irrit. 2 (H319), STOT SE 3 (H336). It is has neurotoxic properties (also according to RISCTOX: http://risctox.istas.net/en/dn_risctox_ficha_sustancia.asp?id_sustancia=957630). Alternative substances: There is no harmonised classification for the alternative substance. Self-classification indicate eye irritant properties (H319) and aquatic chronic and acute properties (H400, H410). There is no entry in the SUBSPORT´s database on hazardous chemicals (SDSC).
Description of Substitution
a) Motivation why to apply the alternative
The company used large amounts of acetone to soak the contaminated machine parts. The contaminated machine parts were collected in a container where acetone was added manually from another large storage container. The parts were soaked then collected manually. They were subsequently wiped with a cloth and dried before being reused in the machines. The acetone was disposed of as hazardous waste. Due to evaporation of acetone and the manual removal of the machine parts, workers were exposed to acetone mostly via inhalation and partly through the skin. The main motivation for substitution was workers health.
b) Description of procedure or technology (including pre-/post-processing)
Contaminated parts are put into the Bio-Circle device with Bio-Circle L liquid and are manually brushed. The washing liquid is reusable up to 6-8 months.
c) Way of application: Dipping and cleaning in an open washer. Manual cleaning with brush.
d) Risk management measures (technical, organizational and personal)
No need for special risk management measures as the liquid is not classified as hazardous under the CLP Regulation. It is free from solvents and VOCs. Nitrile rubber gloves to prevent skin dryness are enough after the substitution.
e) Advantage or disadvantage of alternative
Technical requirements/Advantages:
- Long bath (washing liquid) life
- Special corrosion inhibitors inside Bio-Circle washing liquid provide temporary protection after cleaning
- Washing liquid is warm more acceptable to workers (due to temp. control)
Performance:
Advantage: It is suitable for removing contamination, in particular oils, greases and particle impurities without any human health hazards
Implementation:
- Easy to start unpack, fill liquid in to tank, plug in (220V). Ready to use
- Easy and safe to use
Disposal:
- Less hazardous waste
- Lower related disposal costs
Further aspects:
- NSF-certified
- Non-flammable
- Lower requirements for use of personal protective equipment
Case/substitution evaluation
The alternative has no harmonised classification or known human health hazards and avoids the use of acute toxic VOCs in the cleaning process. It increases the safety at the workplace.
State of implementation
In use
Availability ofAlternative
The alternatives are available on the market.
Producer/Provider
Bio-Circle Surface Technology GmbH https://www.bio-circle.com/
Type of information supplier
User
Contact
The Project Baltic pilot cases on reduction of emissions by substitution of hazardous chemicals and resource efficiency (LIFE Fit for REACH, No.LIFE14ENV/LV000174)
Further information
SDS of applied substances - provided Equipment flyer - provided
Factsheet: Substitution of acetone used for washing contaminated machine parts
Date, reviewed
March 1, 2013